Built in the glass: +5 % of the pre-batch, +0.1 oz of water
Topped
Poured after the melt, kept whole: tonic water 4 oz, no alcohol
Served
2 + 0.1 + 4 = 6.1 oz in the glass, 0.8 oz of it alcohol
Strength
0.8 ÷ 6.1 = 13.1 % ABV as served
Ethanol
0.8 oz × 29.57 ml × 0.789 g/ml = 19 g · about 131 kcal from the alcohol alone
IN THE GLASS
α-PINENE
FROM GIN
Formula
C₁₀H₁₆
Mass
136.24 g/mol
IUPAC
2,6,6-trimethylbicyclo[3.1.1]hept-2-ene
The pine note in juniper berries, and the reason gin tastes like a forest. Co-distilled with the spirit during production. Found in actual pine trees, rosemary, basil, and a good London Dry. The "Christmas tree" smell of gin and the smell of a forest floor share a single molecule.
The cinchona-bark alkaloid that defines tonic water, bitter enough that a few milligrams per liter is all the recipe needs. Used as the original anti-malarial before synthetic replacements; gin & tonic exists because British colonial officers in 19th-century India needed a daily quinine vehicle, and gin made the tonic less unpalatable. Modern tonic carries a fraction of the historical dose.
An orange rind, squeezed, throws a spray that catches the light. That's d-limonene boiling off. It's roughly 95% of orange peel oil by mass, and the molecule that puts the "orange" in orange anything. Used industrially as a green solvent because the chemistry that dissolves citrus oils also dissolves greasy machinery. The expressed-peel garnish on a cocktail is delivering vaporized limonene to the rim of the glass.
Gin, tonic and a lime wedge. Quinine, the bitter alkaloid that once made tonic medicinal, anchors the structure, and alpha-pinene carries the juniper. Carbonation lifts the aromatics; the botanicals do the rest of the work.
PROVENANCE
Quinine, sourced from cinchona bark, was the standard malaria prophylaxis of the 19th century. British officers in India took it in sweetened soda water, the first tonic; gin and lime softened the bitterness further. Schweppes sold Indian Tonic Water from 1870, and the pairing spread well beyond the colonies.